Classification of SHG

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Classification of SHG according to MPGs and parent space group is shown in below table and figure.

MSGs ↓ / Parent SG→With inversion symmetry (wP)Without inversion symmetry (woP)
1. Original MPGs (O)
(Type-I MSGs)
O-wP
Even/odd: from magnetism
O-woP
Even: from magnetism+ crystal
Odd: from magnetism
2. Gray MPGs (G)
(Type-IV MSGs)
G-wP
Even: from magnetism
G-woP
Even: from magnetism + crystal
3. BW MPGs with
PT symmetry (PT)
(Type-III MSGs)
PT-wP
Odd: from magnetism
×
Not possible
4. BW MPGs without PT
nor P symmetry (BW)
(Type-III MSGs)
BW-wP
Even/odd: from magnetism
BW-woP
Even: from magnetism + crystal
Odd: from magnetism

Notation: the symmetry of SHG refer the page of original and gray SHG table and black-white SHG table.

Flow chart to determine the SHG type of magnetic materials. M means the MSP, and the G means the SG of parent phase.

 

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